We have changed our website(新网站地址):






2023
angew chen-2
69. K. Chen, X. Guo, M. Chen*
"Controlled Radical Copolymerization toward Well-Defined Fluoropolymers" 

• Highlighted by 高分子科技!





angew chen
anie202306609-toc-0001-m
68. S. Han, B. Wu, H. Wang, P. Wen, L. Zhang, X. Lin,* M. Chen*
"Designing F/P Hybrid Polymer as Ultrastable Cationic Shielding Interphase for High-Performance Lithium Metal Batteries" 

Selected as VIP by Angew. Chem. Int. Ed.
• Highlighted by 高分子科技!
• Highlighted by 高分子科学前沿!





han toc
angew zhou
67. H. Zhou,# L. Zhang,# P. Wen, Y. Zhou, Y. Zhao, Q. Zhao, Y. Gu., R. Bai, M. Chen*
"Initiator-Activation Strategy Enabled Organocatalyzed Reversible-Deactivation Radical Polymerization Driven by Light" 

• Highlighted by X-Mol!






angew zhou
nature synthesis
66. Y. Zhao, Y. Chen, H. Zhou, Y. Zhou, K. Chen, Y. Gu., M. Chen*
"Controlled Radical Copolymerization of Fluoroalkenes by Using Light-Driven Redox-Relay Catalysis

• Highlighted by Nature Synthesis, Research Briefing!
• Highlighted by 高分子科技!





nature synthesis-toc
图片1
65. L. Zhang, H. Zhou, Y. Gu., M. Chen*
"Light-Driven Organocatalyzed Controlled Radical Polymerization from Sulfonyl Chloride Initiators Promoted by Bis(thiocarbonyl) Disulfides







toc
图片2
64. W. Li, W. Xie, F. Shao, J. Qian, S. Han, P. Wen, J. Lin, M. Chen,* X. Lin*
"Molecular Engineering of Interplanar Spacing via π-Conjugated Phenothiazine Linkages for High-Power 2D Covalent Organic Framework Batteries




fx1_lrg


2022

图片1
64. Y. Zeng,# Q. Quan,# P. Wen, Z. Zhang, M. Chen*
"Organocatalyzed Controlled Radical Copolymerization toward Hybrid Functional Fluoropolymers Driven by Light

• Highlighted by 高分子科技; 中国聚合物网!





scheme 1
图片4
63. Q. Quan, Y. Zhao, K. Chen, H. Zhou, C. Zhou, M. Chen*
"Organocatalyzed Controlled Copolymerization of Perfluorinated Vinyl Ethers and Unconjugated Monomers Driven by Light

• Highlighted by Prof. Benjamin List in Synfacts.





toc
图片3
62. K. Chen, Y. Zhou, S. Han, Y. Liu, M. Chen* 
"Main-Chain Fluoropolymers with Alternating Sequence Control via Light-Driven Reversible-Deactivation Copolymerization in Batch and Flow

• Selected as Hot Paper by Angewandte Chemie!
• Highlighted by 高分子科技; 中国聚合物网!



angew chen kaixuan
2022 CJC zhou
61. Y. Zhou, Y. Fu, M. Chen* 
"Facile control of molecular weight distribution via droplet-flow light-driven reversible-deactivation radical polymerization

• Invited paper for the special issue of Emerging Investigators!
• Highlighted by  Chin. J. Chem!

2022 CJC zhou
图片2
60. Y. Zeng, Y. Zhou, Q. Quan, M. Chen* 
"Facile Access to gem-Trifluoromethyl/Boron-Functionalized Polymers via Free Radical Copolymerization and Cotelomerization





2022 macromolecules zeng yang
2021 WZY CJC cover
59. Z. Wang, Y. Zhou, M. Chen* 
"Computer-Aided Living Polymerization Conducted under Continuous-Flow Conditions

• Invited review for the special issue of Polymer Synthesis!
2021 WZY CJC
图片1
58. Y. Zhou, Q. Quan, M. Chen* 
"Recent Developments of Reversible Deactivation Radical Polymerization in Flow
特约综述



功能高分子学报 zhouyang
57. C. Zhou, H. Zhou, S. Tang, F. Zhang, S. Lei, Z. Li,* M. Chen,* J. Liu*
"Aryl-aryl linked two-dimensional covalent organic frameworks/cellulose composite monolith with hierarchical structure for aqueous dyes adsorption"
J. Appl. Polym. Sci. 2022, 139, e52967.

56. H. Zhou, C. Zhou, S. Tang, F. Zhang, S. Lei, Z. Li,* J. Liu,* M. Chen
"High efficiency solution synthesis of aryl-aryl linked two-dimensional covalent organic frameworks with remarkable adsorption performance for polycyclic aromatic hydrocarbons (PAHs)"
Mater. Lett. 2022, 307, 131002.

2021

aelccp.2021.6.issue-10.largecover
55. M. Ma, F. Shao, P. Wen, K. Chen, J. Li, Y. Zhou, Y. Liu, M. Jia, M. Chen,* X. Lin* 
"Designing Weakly Solvating Solid Main-Chain Fluoropolymer Electrolytes: Synergistically Enhancing Stability toward Li Anodes and High-Voltage Cathodes

• "主链含氟聚合物之弱溶剂化效应" Highlighted by 高分子科技, CBG资讯!



图片1
anie202108417-toc-0001-m
54. Q. Quan, M. Ma, Z. Wang, Y. Gu, M. Chen* 
"Visible-Light Enabled Organocatalyzed Controlled Alternating Terpolymerization of Perfluorinated Vinyl Ethers

• Selected as Cover by Angewandte Chemie!
• Appeared in Hot Topic: Fluorine Chemistry by Angewandte Chemie!
• Appeared in Hot Topic: Photocatalysis by Angewandte Chemie!
2021 angew quan
2021 chem Gu cover
53. Y. Gu, Y. Liu, M. Chen* 
"High-Level Hierarchical Morphology Reinforcing Covalent Adaptable Networks
2021 chem Gu
2021Chen MRC cover
52. Y. Chen, L. Zhang, Y. Jin, X. Lin,* M. Chen* 
"Recent Advances in Living Cationic Polymerization with Emerging Initiation/Controlling Systems


2021 Chen MRC
2021 Jia AFM cover
51. M. Jia, P. Wen, Z. Wang, Y. Zhao, Y. Liu, J. Lin, M. Chen,* X. Lin* 
"Fluorinated bifunctional solid polymer electrolyte synthesized under visible light for stable lithium deposition and dendrite-free all-solid-state batteries


2021 Jia AFM
2021 Gu SCC cover
50. Y. Gu, P. Lin, C. Zhou, M. Chen*
"Machine Learning-assisted systematical polymerization planning: case studies on reversible-deactivation radical polymerization"

• Highlighted by X-Mol, 中国科学化学, 高分子科技: 高分子合成与机器学习:聚合逆分析之“指哪打哪”
2021 Gu SCC
2021 zhou SCC cover
49. Y. Zhou, S. Han, Y. Gu, M. Chen*
"Facile Synthesis of Gradient Copolymers Enabled by Droplet-Flow Photo-Controlled Reversible Deactivation Radical Polymerization"



2021 zhou SCC
2021 ACS AMI wen cover
48. P. Wen, Y. Zhao, Z. Wang, J. Lin, M. Chen,* X. Lin*
"Solvent-Free Synthesis of the Polymer Electrolyte via Photo-Controlled Radical Polymerization: Toward Ultrafast In-Built Fabrication of Solid-State Batteries under Visible Light"


Microsoft Word - am0c21461
2021 Wang macromolecules cover
47. Z. Wang, Y. Gu, M. Ma, Y. Liu, M. Chen*
"Strengthening Polyethylene Thermoplastic through A Dynamic Covalent Networking Additive Based on Alkylboron Chemistry"

 
2021 Wang macromolecules
2021 zhong CS cover
46. F. Zhong, M. Ma, Z. Zhong, X. Lin*, M. Chen*
"Interfacial growth of free-standing PANI films: toward high-performance all-polymer supercapacitors"

2021 zhong CS
2021 zhong cover
45. Z. Zhong, Y. Chen, Y. Zhou, M. Chen*
"Challenges and Recent Developments of Photoflow-Reversible Deactivation Radical Polymerization (RDRP)"

• Invited review for the
special issue of RDRP in CJPS!

2021 zhong CJPS
2020 SCC wang cover
44. E. Wang, K. Chen, Y. Chen, J. Zhang, X. Lin,* M. Chen*
“Porous Polymeric Ligand Promoted Copper-Catalyzed C-N Coupling of (Hetero)Aryl Chlorides under Visible-Light Irradiation"

• Highlighted by 中国科学化学Cu催化C-N成键——给点光照更“灿烂”

2020 SCC wang
2020
2021 gu PC cover
43. Y. Gu, Z. Wang, H. Gong, M. Chen*
"Investigations into CTA-Differentiation-Involving Polymerization of Fluorous Monomers: Exploitation of Experimental Variances in Fine-Tuning of Molecular Weights"

2021 gu PC
42. X. Qing, J. Li, Z. Wang, M. Chen, J. Lin, X. Lin* 
"A functionalized metal organic framework-laden nanoporous polymer electrolyte for exceptionally stable lithium electrodeposition"

2020 CS cover
41. S. Han, Y. Gu, M. Ma, M. Chen*
"Light-Intensity Switch Enabled Nonsynchronous Growth of Fluorinated Raspberry-Like Nanoparticles"

2020 chem sci Han
2020 zhao cover
40. Y. Zhao, M. Ma, X. Lin, M. Chen*
“Photoorganocatalyzed Divergent Reversible-Deactivation Radical Polymerization toward Linear and Branched Fluoropolymers"

• Highlighted by WileyChem!
• Selected as Hot Paper by Angewandte Chemie!
• Appeared in Hot Topic: Fluorine Chemistry by Angewandte Chemie!
2020 angew Zhao
2020 JACS cover
39. K. Jiang, S. Han, M. Ma, L. Zhang, Y. Zhao, M. Chen*
"Photoorganocatalyzed Reversible-Deactivation Alternating Copolymerization of Chlorotrifluoroethylene and Vinyl Ethers under Ambient Conditions: Facile Access to Main-Chain Fluorinated Copolymers"

• Highlighted by
X-Mol and 高分子科技!

2020 JACS
2020 ACS appl mater interfaces cover2
38. Q. Quan, H. Wen, S. Han, Z. Wang, Z. Shao, M. Chen*
"Fluorous-Core Nanoparticle-Embedded Hydrogel Synthesized via Tandem Photo-Controlled Radical Polymerization: Facilitating the Separation of Perfluorinated Alkyl Substances from Water"


2020 ACS appl mater interfaces Quan
2020 OFC zhang cover
37. J. Zhang, E. Wang, Y. Zhou, L. Zhang, M. Chen,* X. Lin*
"A Metal-Free Synthesis of 1,1-Diphenylvinylsulfides with Thiols via Thioetherification under Continuous-Flow Conditions"

2020 OFC zhang
2020 macro zhang cover
36. L. Zhang, K. Jiang, X. Shen, Y. Gu, X. Lin,* M. Chen*
"Thienyl Chloride Initiated Living Cationic Polymerization: A General and Efficient Access toward Terminally Functionalized Poly(vinyl ether)s"

2020 macro zhang
2020 macro wang cover
35. Z. Wang, Y. Gu, M. Ma, M. Chen*
"Strong, Reconfigurable, and Recyclable Thermosets Cross-Linked by Polymer-Polymer Dynamic Interaction based on Commodity Thermoplastics"

2020 macro wang
2020 israel j chem
34. E. Wang, J. Zhang, Z. Zhong, K. Chen, M. Chen*
"Shuttling Catalyst: Facilitating C-C bond formation via cross-couplings with a thermoresponsive polymeric ligand"

• This work is Invited for the sepcial issue of the 2019 Wolf Prize in Chemistry! We are also glad to know that other authors in this issue are Professors of E. Jacobsen (Harvard), D. MacMillan (Princeton), J. Yu (Scripps), P. Baran (Scripps), M. S. Sanford (University of Michigan), M. S. Sigman (University of Utah), G. Molander (UPen), J. Wolfe (University of Michigan), A. Echavarren (ICIQ), R. A. Widenhoefer (Duke University), D. Wang (SIOC), etc. 
2020 israel j chem wang
2020 angew gong cover
33. H. Gong, Y. Gu, Y. Zhao, Q. Quan, S. Han, M. Chen*
"Precise Synthesis of Ultra-High-Molecular-Weight Fluoropolymers Enabled by Chain-Transfer-Agent Differentiation under Visible-Light Irradiation"

• Highlighted by X-Mol!

2019angew
2019
2019 poly chem zhong cover
32. F. Zhong, Y. Zhou, M. Chen*
"The Influence of Mixing on Chain Extension by Photo-Controlled/Living Radical Polymerization under Continuous-Flow Conditions"

2019 poly chem zhong
2019 chem sci wang cover
31. E. Wang, M. Chen*
"Catalyst Shuttling Enabled by a Thermoresponsive Polymeric Ligand: Facilitating Efficient Cross-Couplings with Continuously Recyclable ppm Levels of Palladium"

• This work is selected in 2019 Chemical Science HOT Article Collection. Highlighted by X-Mol and RSC!

2019 chem sci wang
2019 macro zhou cover
30. Y. Zhou, Y. Gu, K. Jiang, M. Chen*
"Droplet-Flow Photopolymerization Aided by Computer: Overcoming the Challenges of Viscosity and Facilitating the Generation of Copolymer Libraries"

• Highlighted by 高分子科学前沿!

2019 macro zhou
2019 JFM gong cover
29. H. Gong, M. Ma, Y. Zhou, Y. Zhao, Y. Gu, M. Chen*
"Photoredox Controlled Living Polymerization"

2019 JFM gong
2018
2018 macro Jiang cover
28. K. Jiang,# L. Zhang,# Y. Zhao, J. Lin, M. Chen*
"Palladium-Catalyzed Cross-Coupling Polymerization: A New Access to Cross-Conjugated Polymers with Modifiable Structure and Tunable Optical/Conductive Properties"

• Highlighted by Prof. Timothy M. Swager "Synthesizing Cross-Conjugated Polymers through Cross-Coupling", Synfacts, 2019, 15, 0144.
• Highlighted by  X-Mol!

2018 cross-conjugation
2018 Poly chem quan cover
27. Q. Quan, H. Gong, M. Chen*
"Preparation of Semifluorinated Poly(meth)acrylates by Improved Photo-Controlled Radical Polymerization without the Use of Fluorinated RAFT Agent: Facilitating Surface Fabrication with Fluorinated Materials"

2018 Poly chem quan
2018 synlett gong cover
26. H. Gong, Y. Gu, M. Chen*
"Controlled/Living Radical Polymerization of Semifluorinated (Meth)acrylates"

2018 syn
2018 macro zhao cover
25. Y. Zhao, H. Gong, K. Jiang, S. Yan, J. Lin and M. Chen*
"Organocatalyzed Photoredox Polymerization from Aromatic Sulfonyl Halides: Facilitating Graft from Aromatic C-H Bonds"

2018 macro zhao
2018 chem sci wang cover
24. X. Shen, H. Gong, Y. Zhou, Y. Zhao, J. Lin,* M. Chen*
“Unsymmetrical Difunctionalization of Cyclooctadiene under Continuous Flow Conditions: Expanding the Scope of Ring Opening Metathesis Polymerization”

X Sheng
2018 angew gong cover
23. H. Gong, Y. Zhao, X. Shen, J. Lin, M. Chen*
“Organocatalyzed Photocontrolled Radical Polymerization of Semi-fluorinated (Meth)acrylates Driven by Visible Light”

• Highlighted by X-Mol.

2018 gong angew
Before
22. W. Zhang, M. Huang, S. Abdullatif, M. Chen, Y. Shao-Horn,  J. A. Johnson,* "Reduction of (Meth)acrylate-Based Block Copolymers Provides Access to Self-Assembled Materials with Ultrasmall Domains", Macromolecules 2018, 51, 6757–6763.

21. M. Huang,# S. Feng,# W. Zhang, L. Giordano, M. Chen, C. V. Amanchukwu, R. Anandakathir, Y. Shao-Horn,* J. A. Johnson,* "Fluorinated Aryl Sulfonimide Tagged (FAST) salts: modular synthesis and structure–property relationships for battery applications", Energy Environ. Sci. 2018, 11, 1326-1334.

20. S. Feng,# M. Chen,# L. Giordano, M. Huang, W. Zhang, C. V. Amanchukwu, R. Anandakathir, Y. Shao-Horn* and J. A. Johnson,* "Mapping a stable solvent structure landscape for aprotic Li–air battery organic electrolytes", J. Mater. Chem. A 2017, 5, 23987-23998.

19. Y. Gu, K. Kawamoto, M. Zhong, M. Chen, M. J. A. Hore, A. M. Jordan, L. T. J. Korley, B. D. Olsen, J. A. Johnson,* "Semibatch Monomer Addition as a General Method to Tune and Enhance the Mechanics of Polymer Networks via Loop-defect Control", Proc. Natl. Acad. Sci. U.S.A. 2017, 114, 4875-4880.

18. M. Chen, S. Deng, Y. Gu, J. Lin, M. J. MacLeod, J. A. Johnson,* “Logic-Controlled Radical Polymerization with Heat and Light: Multiple-Stimuli Switching of Polymer Chain Growth via a Recyclable, Thermally Responsive, Gel Photo-Redox Catalyst”, J. Am. Chem. Soc. 2017, 139, 2257-2266.

17. M. Chen,# Y. Gu,# A. Singh, M. Zhong, A. M. Jordan, S. Biswas, L. T. J. Korley, A. C. Balazs, J. A. Johnson,* ''Living Additive Manufacturing: Transformation of Parent Gels into Diversely Functionalized Daughter Gels Made Possible by Visible Light Photoredox Catalysis'', ACS Cent. Sci. 2017, 3, 124-134.

16. M. Chen,# M. Zhong,# J. A. Johnson,* “Light-Controlled Radical Polymerization: Mechanisms, Methods, and  Applications”, Chem. Rev. 2016, 116, 10167−10211.

15. M. Chen, J. A. Johnson*, “Improving Photo-controlled Living Radical Polymerization from Trithiocarbonates through the Use of Continuous-flow Techniques", Chem. Commun. 2015, 51, 6742-6745.

14. M. Chen, M. J. MacLeod, Jeremiah A. Johnson,* “Visible-Light-Controlled Living Radical Polymerization from a Trithiocarbonate Iniferter Mediated by an Organic Photoredox Catalyst", ACS Macro Lett. 2015, 4, 566−569.

13. M. Chen, S. Ichikawa, S. L. Buchwald*, “Rapid and Efficient Copper-Catalyzed Finkelstein Reaction of (Hetero)Aromatics under Continuous-Flow Conditions", Angew. Chem. Int. Ed. 2015, 54, 263-266.

12. M. Chen, S. L. Buchwald*, “Rapid and Efficient Trifluoromethylation of Aromatic and Heteroaromatic Compounds Using Potassium Trifluoroacetate Enabled by a Flow System", Angew. Chem. Int. Ed. 2013, 52, 11628-11631.

11. M. Chen, S. L. Buchwald*, "Continuous-Flow Synthesis of 1-Substituted Benzotriazoles from Chloronitrobenzenes and Amines in a C-N Bond Formation/Hydrogenation/ Diazotization/ Cyclization Sequence",  Angew. Chem. Int. Ed. 2013, 52, 4247-4250.

10. M. Chen, X. Zheng, W. Li, J. He, A. Lei*, “Palladium-Catalyzed Aerobic Oxidative Cross-Coupling Reactions of Terminal Alkynes with Alkylzinc Reagents", J. Am. Chem. Soc. 2010, 132, 4101-4103.

9. M. Chen, J. Wang, Z. Chai, C. You, A. Lei*, “C-X (X=Br, I) Bond-Tolerant Aerobic Oxidative Cross-Coupling: A Strategy to Selectively Construct β-Aryl Ketones and Aldehydes", Adv. Synth. Catal. 2012, 354, 341-346.

8. M. Chen, Y. Weng, A. Lei*, "Asymmetric Cycloisomerization of 1, n-Enynes Catalyzed by Transition Metals", Progress in Chemistry, 2010, 22, 1341-1352.

7. A. Lei*, W. Liu, C. Liu, M. Chen, "Arylation of Unactivated Arenes", Dalton Trans. 2010, 39, 10352-10361.

6. W. Yin, C. He, M. Chen, H. Zhang, A. Lei*, "Nickel-Catalyzed Oxidative Coupling Reaction of Two Different Terminal Alkynes Using O2 as the Oxidant at Room Temperature: Facile Syntheses of Unsymmetric 1,3-Diynes",  Org. Lett. 2009, 11, 709-712

5. M. Chen, Y. Weng, M. Guo, H. Zhang, A. Lei*, "Nickel-Catalyzed Reductive Cyclization of Unactivated 1, 6-Enynes in the Presence of Organozinc Reagents",  Angew. Chem. Int. Ed. 2008, 47, 2279-2282.

4. C. Liu, C. He, W. Shi, M. Chen, A. Lei*, "Ni-Catalyzed Mild Arylation of α-Halocarbonyl Compounds with Arylboronic Acids", Org. Lett. 2007, 9, 5601-5604.

3. A. Lei*, M. Chen, M. He, X. Zhang, "Asymmetric Hydrogenation of Pyridines: Enantioselective Synthesis of Nipecotic Acid Derivatives", Eur. J. Org. Chem. 2006, 4343-4347.

2. L.-J. Deng, J. Liu, J.-Q. Huang, Y. Hu, M. Chen, Y. Lan, J.- H. Chen, A. Lei, Z. Yang*, "Effect of lithium chloride on tuning the reactivity of Pauson- Khand reactions catalyzed by palladium-tetramethylthiourea",  Synthesis 2007, 16, 2565-2570.

1. L.-S. Cai, S.-L. Gong, M. Chen, C.-Y. Wu*, "Vinyl Crown Ether as a Novel Radical Crosslinked Sol-Gel SPME Fiber for Determination of Organophosphorus Pesticides in Food Samples",  Anal. Chim. Acta 2006, 559, 89-96.